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41.
 The paleoceanography in the Nordic seas was characterized by apparently repeated switching on and off of Atlantic water advection. In contrast, a continous influx of Atlantic waters probably occurred along the northern Barents Sea margin during the last 150 ka. Temporary ice-free conditions enhanced by subsurface Atlantic water advection and coastal polynyas accelerated the final ice sheet build-up during glacial times. The virtually complete dissolution of biogenic calcite during interglacial intervals was controlled mainly by CO2-rich bottom waters and oxidation of higher levels of marine organic carbon and indicates intensive Atlantic water inflow and a stable ice margin. Received: 25 February 1997 / Revision received: 4 March 1998  相似文献   
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43.
Biomarker molecules are valuable for the elucidation of ancient microbial ecosystems and the characterization of petroleum source rocks. For such studies, acquisition of reliable hydrocarbon data and proof of their syngeneity are essential. However, contamination of geological samples with anthropogenic petroleum products during drilling, storage and sampling can be particularly problematic because these hydrocarbons may over-print an original indigenous biomarker profile. To evaluate the extent of contamination of drill core and outcrop material, we studied the distribution of hydrocarbons in 26 rocks from different locations in the world. All rocks had petroleum products on their exterior surfaces. Twenty-two samples also contained surficial hydrocarbons derived from polyethylene plastic, including branched alkanes with quaternary carbon centers (BAQCs) and alkylcyclopentanes with pronounced even-over-odd carbon number preference. Using three examples from the Paleoproterozoic Tawallah and McArthur Groups in northern Australia, we show how indigenous biomarkers can be recognized by comparing hydrocarbon distributions between exterior rock surfaces and the rock interior, and how infiltration of allochthonous hydrocarbons can be assessed through the spatial distribution of characteristic polyethylene derived hydrocarbons in the rock. The methods outlined in this paper give confidence in the interpretation of biomarkers in particularly sensitive applications such as the first occurrences of certain organisms in the geological record and the provenance of organic matter in meteorites.  相似文献   
44.
Based upon a compilation and analysis of O-isotope data for Neogene volcanic rocks worldwide, the 18O variation for 743 basalts (historic lavas, submarine glasses, and lavas with <0.75 wt% H2O) is +2.9 to +11.4. Mid-ocean-ridge basalt (MORB) has a uniform O-isotope composition with 180=+5.7±0.2. Basalts erupted in different tectonic settings have mean 18O/16O ratios that are both lower and higher than MORB, with continental basalts enriched in 18O by ca. 1 over oceanic basalts. The 18O range for the subset of 88 basalts with Mg# [100·Mg(Mg+Fe2+)] 75–68, considered to be unmodified primary mantle partial melts, is +3.6 to +8.7. These features are a clear indication that: (1) the Earth's upper mantle is heterogeneous with respect to its O-isotope composition; (2) that both low-18O and high-18O reservoirs have contributed to basalt petrogenesis. Large-ion lithophile element-enriched basalts associated with subduction at convergent plate margins are slightly enriched in 18O, a characteristic that is considered to be an intrinsic feature of the subduction process. Intraplate oceanic and continental basalts have highly variable 18O/16O ratios, with individual localities displaying 18O ranges in excess of 1.5 to 2. Systematic co-variations between O-, Sr-, Nd-, and Pb-isotope ratios reflect the same principal intramantle end-member isotopic components (DMM, HIMU, EM-I, EM-II) deduced from radiogenic isotope considerations and, therefore, imply that a common process is responsible for the origin of upper mantle stable and radiogenic isotope heterogeneity, namely the recycling of lithospheric material into the mantle.  相似文献   
45.
The future information needs of stakeholders for hydrogeological and hydro‐climate data management and assessment in New Zealand may be met with an Open Geospatial Consortium (OGC) standards‐compliant publicly accessible web services framework which aims to provide integrated use of groundwater information and environmental observation data in general. The stages of the framework development described in this article are search and discovery as well as data collection and access with (meta)data services, which are developed in a community process. The concept and prototype implementation of OGC‐compliant web services for groundwater and hydro‐climate data include demonstration data services that present multiple distributed datasets of environmental observations. The results also iterate over the stakeholder community process and the refined profile of OGC services for environmental observation data sharing within the New Zealand Spatial Data Infrastructure (SDI) landscape, including datasets from the National Groundwater Monitoring Program and the New Zealand Climate Database along with datasets from affiliated regional councils at regional‐ and sub‐regional scales. With the definition of the New Zealand observation data profile we show that current state‐of‐the‐art standards do not necessarily need to be improved, but that the community has to agree upon how to use these standards in an iterative process.  相似文献   
46.
Knowledge of landscape type can inform cartographic generalization of hydrographic features, because landscape characteristics provide an important geographic context that affects variation in channel geometry, flow pattern, and network configuration. Landscape types are characterized by expansive spatial gradients, lacking abrupt changes between adjacent classes; and as having a limited number of outliers that might confound classification. The US Geological Survey (USGS) is exploring methods to automate generalization of features in the National Hydrography Data set (NHD), to associate specific sequences of processing operations and parameters with specific landscape characteristics, thus obviating manual selection of a unique processing strategy for every NHD watershed unit. A chronology of methods to delineate physiographic regions for the United States is described, including a recent maximum likelihood classification based on seven input variables. This research compares unsupervised and supervised algorithms applied to these seven input variables, to evaluate and possibly refine the recent classification. Evaluation metrics for unsupervised methods include the Davies–Bouldin index, the Silhouette index, and the Dunn index as well as quantization and topographic error metrics. Cross validation and misclassification rate analysis are used to evaluate supervised classification methods. The paper reports the comparative analysis and its impact on the selection of landscape regions. The compared solutions show problems in areas of high landscape diversity. There is some indication that additional input variables, additional classes, or more sophisticated methods can refine the existing classification.  相似文献   
47.
A three-dimensional σ-coordinate ocean model with realistic forcing is used to derive and compare flushing time, residence time and water age distributions in Bass Strait, a broad shallow shelf sea in south-eastern Australia which exhibits seasonal variation in water mass properties and circulation. Results illustrate flushing out of most old water occurs each winter–spring period and the circulation in summer increases age of remnant older water in the Strait. A correlation between water age and salinity is found in winter which is the result of advective “erosion” of the interior water mass. The presence of an area in the south-eastern part of the interior with low flushing is suggested to result from a number of physical factors including the presence of quasi-stationary eddies which entrain age, leading to relatively older water residing there.  相似文献   
48.
The partitioning of stable carbon isotopes between calcite, graphite and CO2 was experimentally determined at temperatures from 500 to 1200 °C and 1 to 15 kbar pressure. Attainment of carbon isotope equilibrium in CO2-calcite runs was proven by achieving the same fractionation from isotopically opposite directions. The resultant CO2-calcite fractionation curve for carbon differs from Bottinga's calculation by 1.2 and confirms recent experiments of Chacko et al. and Mattey et al. In CO2-graphite experiments equilibrium fractions were extrapolated by applying the partial-exchange technique of Northrop and Clayton and by optimizing the contribution of surface reaction in graphite. CO2-graphite fractionations at temperatures up to 800 °C are in fair agreement with Bottinga's calculation, but yield a surprisingly high fractionation of 5 at upper mantle temperatures. The combination of CO2-calcite (carbon) and CO2-graphite fractionation results in a new experimentally determined calcite-grapite fractionation curve, expressed by the equation:
  相似文献   
49.
The cluster Praesepe (age ∼650 Myr) is an ideal laboratory to study stellar evolution. Specifically, it allows us to trace the long-term decline of rotation and activity on the main sequence. Here, we present rotation periods measured for five stars in Praesepe with masses of 0.1–0.5 M– the first rotation periods for members of this cluster. Photometric periodicities were found from two extensive monitoring campaigns, and are confirmed by multiple independent test procedures. We attribute these variations to magnetic spots co-rotating with the objects, thus indicating the rotation period. The five periods, ranging from 5 to 84 h, show a clear positive correlation with object mass, a trend which has been reported previously in younger clusters. When comparing with data for F–K stars in the coeval Hyades, we find a dramatic drop in the periods at spectral type K8–M2 (corresponding to 0.4–0.6 M). A comparison with periods of very low mass (VLM) stars in younger clusters provides a constraint on the spin-down time-scale: we find that the exponential rotational braking time-scale is clearly longer than 200 Myr, most likely 400–800 Myr. These results are not affected by the small sample size in the rotation periods in Praesepe. Both findings, the steep drop in the period–mass relation and the long spin-down time-scale, indicate a substantial change in the angular momentum loss mechanism for VLM objects, possibly the breakdown of the solar-type (Skumanich) rotational braking. While the physical origin for this behaviour is unclear, we argue that parts of it might be explained by the disappearance of the radiative core and the resulting breakdown of an interface-type dynamo in the VLM regime. Rotational studies in this mass range hold great potential to probe magnetic properties and interior structure of main-sequence stars.  相似文献   
50.
The Schleenhain open pit coal mine, located 30 km south of Leipzig, Germany, exposes Upper Eocene and Oligocene non-marine strata representing fluvial deposition in the centre of the Weisselster Basin. Active mining and successive cuts provided the rare opportunity to obtain a three-dimensional perspective of laterally extensive surface outcrops. These were used to construct a detailed fence diagram, which provided the basis for recognition of key architectural elements in the weakly consolidated meandering stream deposits. In addition to the eight basic architectural elements of Miall (1985 ), the element SL (shallow lake deposits) was newly defined and the element CH (channel) was subdivided into CHg (palaeo-river system) and CHk (small channel). The profiles contain parts of two fining-upward cycles, which are separated by an unconformity spanning the Early Oligocene. Deposits of the first cycle begin with transverse sand bars (downstream accretion deposits-DA) and point bars (lateral accretion deposits-LA). The upper part of the cycle is represented by overbank fines (OF) and the element SL, which consists of laterally discontinuous lenses of dark, plant-bearing, kaolinite-rich clays, that were deposited in shallow lakes adjacent to the active channel. Coal seams interlayered with palaeosols are the main constituents of element OF. Sheetlike bodies of medium to fine gravels (gravel bars and bedforms-GB) on an erosive coal surface mark the beginning of the second cycle. Dissolution of underlying Permian salts and sulphates prior to, during, and after the deposition of the Palaeogene strata caused the development of two synclines within the outcrop. Coal seams and clay horizons which thicken and dip towards the centre of the synclines, provide evidence for their chronological development.  相似文献   
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